Product ID:PICLORAM METHYL ESTER 100 UG/ML IN METHANOL, F2155S
MSDS Date:07/14/1992
FSC:6810
NIIN:00N052596
MSDS Number: BVMPJ

CHEM SERVICE INC

WEST CHESTER, PA 19381
US

Emergency Phone: 215-692-3026

Info Phone: 215-692-3026

Cage: 84898

CHEM SERVICE, INC

599 WEST CHESTER, PA 19301-9650 US

Telephone: 610-692-3026

Cage: 8Y898

METHANOL; (METHYL ALCOHOL) (SARA III) (CONTAINING ING 2).

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PICOLINIC ACID, 4-AMINO-3,5,6-TRICHLORO-; (PICLORAM METHYL

CAS: 1918-02-1

RTECS: TJ7525000

Fraction By Weight: <0.1%

OSHA PEL N/K

ACGIH TLV: N/K

ARRIVED. GET MEDICAL ATTENTION IF NECESSARY.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF ABSORBED THROUGH SKIN
OR INHALED! MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. REPEATED
EXPOSURE TO VAPORS &/OR DUST CAN CAUSE EYE INJURY. CAN CAUSE
GASTRO-INTESTINAL DISTURBANCES. EX POSURE CAN CAUSE LIVER OR KIDNEY
DAMAGE. CAN CAUSE CARDIOVASCULAR SYSTEM INJURY. CAN CAUSE
CONVULSIONS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:AN ANTIDOTE IS A SUBSTANCE INTENDED TO COUNTERACT EFT OF A
POISON. IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMERGENCY PERS. MED
ADVICE CAN BE OBTAINED FROM POIS CTL CTR. INGEST:CALL MD IMMED .
EYES :FLUSH CONTINUOUSLY W/WATER FOR AT LST 15-20 MINS. SKIN:FLUSH
W/WATER FOR 15-20 MINS. IF NO BURNS HAVE OCCURRED - USE SOAP &
WATER TO CLEANSE SKIN. DO NOT WEAR SHOES/CLTHG UNTIL ABSOLUTELY
(SUPDAT)

Flash Point:51.8F,11.0C
Lower Limits:6.7%
Upper Limits:36%
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL POWDER. DO NOT USE
WATER!
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS IS A FLAMMABLE CHEMICAL.

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA REGULATED
EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR
MATERIAL. SWEEP UP & PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR
DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:ALL CHEMICAL SHOULD BE CONSIDERED
HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT. FLAMMABLE. HYGROSCOPIC.
AVOID CONTACT W/SKIN, EYES & CLOTHING.
Other Precautions:DO NOT BREATHE VAPORS. KEEP TIGHTLY CLOSED. THIS
PRODUCT IS FURNISHED FOR LABORATORY USE ONLY! MFR'S PRODUCTS MAY
NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL OR PESTICIDAL
PRODUCTS, FOOD ADDITIVES O R AS HOUSEHOLD CHEMICALS.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:USE APPROPRIATE NIOSH/MSHA APPROVED SAFETY
EQUIPMENT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:ACID HALIDES & ANHYDRIDES. FIRST AID PROC:FREE OF ALL
CHEM ODORS. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYGEN IF
PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT HAS STOPPED BRTHG ADMIN
A RTF RESP. IF PATIENT IS IN CARDIAC ARREST ADMIN CPR. CONTINUE
LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS (ING 3)

Boiling Pt:B.P. Text:148F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:97 @ 20C
Vapor Density:1.11
Spec Gravity:0.791
Solubility in Water:MISCIBLE
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
INCOMPAT W/STRONG ACIDS, STRONG OXIDIZING AGENTS, STRONG REDUCING
AGENTS, ACTIVE METALS (E.G. SODIUM). REACTS W/(SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER
& SCRUBBER.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.